烯丙型亚砜在P(OMe)3存在下加热，发生[2,3]-σ重排，形成次磺酸酯，进而在P(OMe)3作用下转化为烯丙醇。该反应立体选择性高，且可以预测。

反应机理

反应实例

参考文献

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摘自：有机人名反应——机理及应用 第四版，Strategic Applications of Named Reactions in Organic Synthesis