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图片来源:J. Am. Chem. Soc.
图片来源:J. Am. Chem. Soc.
图片来源:J. Am. Chem. Soc.
图片来源:J. Am. Chem. Soc.
在较强酸的存在下,含有悬垂基团的络合物的活性变得更依赖氧气,这也就意味着Co(III)-超氧化物的质子化成为了速率决定步骤。
图片来源:J. Am. Chem. Soc.
参考文献:Pendent Relay Enhances H2O2 Selectivity during Dioxygen Reduction Mediated by Bipyridine-Based Co−N2O2 Complexes
J. Am.Chem. Soc. 2021, /jacs.1c03381
原文作者:Asa W. Nichols, Emma N. Cook, Yunqiao J. Gan, PeterR. Miedaner, Julia M. Dressel, Diane A. Dickie, Hannah S. Shafaat, and Charles W. Machan*
https://pubs.acs.org/doi/pdf/10.1021/jacs.1c03381
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